One-dimensional catena – polymer [[ bis(µ-hydroxido) bis(aqua) (O1 : O1’) Sodium(1)] bis-{(µ-hydroxido)(hydroxido) 2 (2,6-pydc-k -N, O1, O2)Cu(II)}]

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Published: Jan 28, 2023
DOI: https://doi.org/10.64095/ajst.v1i1.54
Keywords:
Heterometallic; 2,6-pyridinedicarboxylic acid; coordination polymer; onedimensional; octahedra

Main Article Content

Fatima Ghalbououn
Chemistry Department Tripoli-University, Tripoli-Libya
Ramadan Abuhmaiera
Chemistry Department, Faculty of Science, University of Tripoli
Fathia Treish
Chemistry Department, Faculty of Science, University of Tripoli
Ramadan Elmehdawi
Chemistry Department, Faculty of Science, University of Tripoli

Abstract

The new title one-dimensional hetero-tri-nuclear Cu2–Na coordination polymer
[NaCu2(Hpydc)2(H2O)2(OH)3]n [1] was isolated as a green solid by heating a mixture of 2,6-
pyridine dicarboxylic acid with Cu (NO3)2 in methanol in the presence of NaOH. The
coordination polymer has been characterized by FTIR and X-ray single crystal diffraction. It
consists of two dependent Copper (II) centers bridged by a hydroxyl group and each bridged
by sodium cation through a hydroxy bridge and carboxylate oxygen-atoms of HL- ligand
(where H2pydc = pyridine 2,6- dicarboxylic acid).

Article Details

How to Cite
Ghalbououn, F., Abuhmaiera, R., Treish, F., & Elmehdawi, R. (2023). One-dimensional catena – polymer [ bis(µ-hydroxido) bis(aqua) (O1 : O1’) Sodium(1)] bis-{(µ-hydroxido)(hydroxido) 2 (2,6-pydc-k -N, O1, O2)Cu(II)}] . Academic Journal of Science and Technology, 1(1), 114–117. https://doi.org/10.64095/ajst.v1i1.54
Issue
Vol. 1 No. 1 (2023): Academic Journal of Science and Technology
Section
Basic sciences

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